NodeMCU is famous for the ESP8266E module with the LUA programming language. Now, this is a more powerful NodeMCU with ESP32 on it.
ESP32 is the big brother of ESP8266. It comes with dual-core 32-bit processor, built-in WiFi and Bluetooth, more RAM and Flash memory, more GPIO, more ADC, and many other peripherals :)
NodeMCU ESP32 is an ESP-WROOM-32 module in breadboard friendly form factor, you can develop your project by using this compact microcontroller on a breadboard.
EMCU.